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Title: Kinetics of the gas phase reactions of chlorine atoms with a series of ketones
Journal: Chem. Phys. Lett.
Volume: 431
Page(s): 257 - 260
Year: 2006
Reference type: Journal article
Squib: 2006TAK/MAT257-260
Reaction:
(C2H5)2CO + Cl → Products
Reaction order:
2
Temperature:
296
K
Pressure: 0.93 bar
Rate expression:
8.1x10-11 [±8.5x10-12 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
In real time
Analytical technique:
Fourier transform (FTIR)
Comments:
The kinetic of reaction was measured relative to reactions C2H2 + Cl -> products and C2H4 + Cl -> products
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