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Title: OH reaction rate constants and UV absorption cross-sections of unsaturated esters
Journal: Atmos. Environ.
Volume: 40
Page(s): 3764 - 3772
Year: 2006
Reference type: Journal article
Squib: 2006TER/LAN3764-3772
Reaction:
CH2=CHCOOC2H5 + ·OH → Products
Reaction order:
2
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
1.7x10-11 [±4.0x10-12 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
The rate constants was measured relatively to the rate constants of OH with isobutanol and cyclohexane
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