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Accessibility information
Author(s):   Tsang, W.
Title:   Mechanism and rate constants for the decomposition of 1-pentenyl radicals
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   8501 - 8509
Year:   2006
Reference type:   Journal article
Squib:   2006TSA8501-8509

Reaction:   CH2=CHCHCH2CH31,3-Butadiene + ·CH3
Reaction order:   1
Temperature:   500 - 2000 K
Rate expression:   1.02x1014 [s-1] (T/298 K)0.10 e-150200 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Pressure dependence:   Rate constant is high pressure limit
Comments:   The log(k/k) values at various pressures were presented in four parameters form

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
500 2.18E-2
600 9.16E0
700 6.86E2
800 1.75E4
900 2.18E5
1000 1.64E6
1100 8.54E6
1200 3.39E7
1300 1.09E8
1400 2.95E8
1500 7.03E8
1600 1.50E9
1700 2.94E9
1800 5.33E9
1900 9.09E9
2000 1.47E10