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Title: Mechanism and rate constants for the decomposition of 1-pentenyl radicals
Journal: J. Phys. Chem. A
Volume: 110
Page(s): 8501 - 8509
Year: 2006
Reference type: Journal article
Squib: 2006TSA8501-8509
Reaction:
CH2=CHCHCH2CH3 → 1,3-Butadiene + ·CH3
Reaction order:
1
Temperature:
500 - 2000
K
Rate expression:
1.02x1014 [s-1] (T/298 K)0.10 e-150200 [J/mole]/RT
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
Pressure dependence:
Rate constant is high pressure limit
Comments:
The log(k∞/k) values at various pressures were presented in four parameters form
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 500 | 2.18E-2 |
| 600 | 9.16E0 |
| 700 | 6.86E2 |
| 800 | 1.75E4 |
| 900 | 2.18E5 |
| 1000 | 1.64E6 |
| 1100 | 8.54E6 |
| 1200 | 3.39E7 |
| 1300 | 1.09E8 |
| 1400 | 2.95E8 |
| 1500 | 7.03E8 |
| 1600 | 1.50E9 |
| 1700 | 2.94E9 |
| 1800 | 5.33E9 |
| 1900 | 9.09E9 |
| 2000 | 1.47E10 |