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Accessibility information
Author(s):   Tsang, W.
Title:   Mechanism and rate constants for the decomposition of 1-pentenyl radicals
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   8501 - 8509
Year:   2006
Reference type:   Journal article
Squib:   2006TSA8501-8509

Reaction:   CH2=CHCH(CH3)CH2·1,3-Butadiene + ·CH3
Reaction order:   1
Temperature:   500 - 2000 K
Rate expression:   4.67x1012 [s-1] (T/298 K)0.42 e-128100 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Pressure dependence:   Rate constant is high pressure limit
Comments:   The log(k/k) values at various pressures were presented in four parameters form

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
500 2.41E-1
600 4.42E1
700 1.85E3
800 3.06E4
900 2.73E5
1000 1.58E6
1100 6.68E6
1200 2.23E7
1300 6.18E7
1400 1.49E8
1500 3.19E8
1600 6.23E8
1700 1.13E9
1800 1.91E9
1900 3.06E9
2000 4.69E9