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Title: Kinetics of the gas phase reactions of chlorine atoms with a series of formates
Journal: Chem. Phys. Lett.
Volume: 432
Page(s): 57 - 61
Year: 2006
Reference type: Journal article
Squib: 2006WAL/HUR57-61
Reaction:
HCOOCH2CH2CH3 + Cl → Products
Reaction order:
2
Temperature:
296
K
Pressure: 0.93 bar
Rate expression:
4.65x10-11 [±4.7x10-12 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
In real time
Analytical technique:
Fourier transform (FTIR)
Comments:
The rate constant was measured relative reaction Cl+C2H2 and Cl+C2H5Cl
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