Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Cavallotti, C.; Mancarella, S.; Rota, R.; Carra, S.
Title:   Conversion of C5 into C6 cyclic species through the formation of C7 intermediates
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   3959 - 3969
Year:   2007
Reference type:   Journal article
Squib:   2007CAV/MAN3959-3969

Reaction:   TolueneNorcaradiene
Reaction order:   1
Temperature:   1000 - 2500 K
Rate expression:   6.12x1013 [s-1] (T/298 K)0.42 e-365682 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 8.10E-6
1100 4.60E-4
1200 1.33E-2
1300 2.32E-1
1400 2.68E0
1500 2.24E1
1600 1.44E2
1700 7.43E2
1800 3.20E3
1900 1.19E4
2000 3.86E4
2100 1.12E5
2200 2.96E5
2300 7.21E5
2400 1.63E6
2500 3.45E6