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Accessibility information
Author(s):   Cavallotti, C.; Mancarella, S.; Rota, R.; Carra, S.
Title:   Conversion of C5 into C6 cyclic species through the formation of C7 intermediates
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   3959 - 3969
Year:   2007
Reference type:   Journal article
Squib:   2007CAV/MAN3959-3969

Reaction:   TolueneBenzyl +
Reaction order:   1
Temperature:   1000 - 2500 K
Rate expression:   7.79x1014 [s-1] (T/298 K)0.68 e-373213 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 5.70E-5
1100 3.60E-3
1200 1.15E-1
1300 2.15E0
1400 2.66E1
1500 2.37E2
1600 1.60E3
1700 8.71E3
1800 3.93E4
1900 1.51E5
2000 5.11E5
2100 1.54E6
2200 4.19E6
2300 1.05E7
2400 2.44E7
2500 5.29E7