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Accessibility information
Author(s):   Jasper, A.W.; Klippenstein, S.J.; Harding, L.B.; Ruscic, B.
Title:   Kinetics of the reaction of methyl radical with hydroxyl radical and methanol decomposition
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   3932 - 3950
Year:   2007
Reference type:   Journal article
Squib:   2007JAS/KLI3932-3950

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2007JAS/KLI3932-3950   ·CH3 + ·OHCH3OH  300 - 2500   9.31E-11   -0.02   -139      2
  2007JAS/KLI3932-3950   ·CH3 + ·OH → CH2(X3B_1) + H2O  300 - 2500   1.61E-13   2.57   1.67E04      2
    2007JAS/KLI3932-3950   CH2(1) + H2OCH3OH  300 - 2500                  2
  2007JAS/KLI3932-3950   CH2O + H2CH3OH  300 - 2500   2.28E-11       2.92E05      2
  2007JAS/KLI3932-3950   trans-HCOH + H2CH3OH  300 - 2500   1.25E-14   2.62   3.72E04      2
  2007JAS/KLI3932-3950   cis-HCOH + H2CH3OH  300 - 2500   3.11E-14   2.27   3.43E04      2
  2007JAS/KLI3932-3950   CH3 + CH3OH  300 - 2500   1.59E-10   0.24   -217      2
  2007JAS/KLI3932-3950   (·)CH2OH + CH3OH  300 - 2500   2.89E-10   0.04          2
    2007JAS/KLI3932-3950   ·CH3 + ·OHCH3OH  300 - 3000                  3
    2007JAS/KLI3932-3950   ·CH3 + ·OH → CH2(1) + H2O  300 - 3000                  2
    2007JAS/KLI3932-3950   ·CH3 + ·OHCH2O + H2  300 - 3000                  2
    2007JAS/KLI3932-3950   ·CH3 + ·OH → trans-HCOH + H2  300 - 3000                  2
    2007JAS/KLI3932-3950   ·CH3 + ·OH → cis-HCOH + H2  300 - 3000                  2
  2007JAS/KLI3932-3950   ·CH3 + ·OH(·)CH2OH +   300 - 3000   3.18E-12   1.00   1.34E04      2
  2007JAS/KLI3932-3950   ·CH3 + ·OHCH3 +   300 - 3000   6.45E-13   1.01   5.00E04      2
  2007JAS/KLI3932-3950   ·CH3 + ·OH → CH2(1) + H2O  300 - 3000   1.09E07   4.10   -5197      1
  2007JAS/KLI3932-3950   ·CH3 + ·OH → trans-HCOH + H2  300 - 3000   7.58E04   6.22   -1.31E04      1
  2007JAS/KLI3932-3950   ·CH3 + ·OH → cis-HCOH + H2  300 - 3000   3.03E04   6.41   -1.04E04      1
  2007JAS/KLI3932-3950   ·CH3 + ·OHCH2O + H2  300 - 3000   2502   6.72   -1.26E04      1
  2007JAS/KLI3932-3950   ·CH3 + ·OH(·)CH2OH +   300 - 3000   1.45E07   5.01   7894      1
  2007JAS/KLI3932-3950   ·CH3 + ·OHCH3 +   300 - 3000   1.76   18.59   -114      1
    2007JAS/KLI3932-3950   CH3OH·CH3 + ·OH  1000 - 3000                  2
    2007JAS/KLI3932-3950   CH3OH → CH2(1) + H2O  1000 - 3000                  2
    2007JAS/KLI3932-3950   CH3OH → trans-HCOH + H2  1000 - 3000                  2
    2007JAS/KLI3932-3950   CH3OH → cis-HCOH + H2  1000 - 3000                  2
    2007JAS/KLI3932-3950   CH3OH(·)CH2OH +   1000 - 3000                  2
  2007JAS/KLI3932-3950   CH3OH·CH3 + ·OH  1000 - 3000   6.28E16   -0.61   3.87E05      1
  2007JAS/KLI3932-3950   CH3OH → CH2(1) + H2O  1000 - 3000   9.51E15   -1.02   3.84E05      1
  2007JAS/KLI3932-3950   CH3OH → trans-HCOH + H2  1000 - 3000   1.91E12   1.65   3.55E05      1
  2007JAS/KLI3932-3950   CH3OH → cis-HCOH + H2  1000 - 3000   2.38E12   1.61   3.68E05      1
  2007JAS/KLI3932-3950   CH3OH(·)CH2OH +   1000 - 3000   2.30E10   5.04   3.53E05      1

Search returned 31 records.