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Home ©NIST, 2013 Accessibility information |
Title: A comprehensive kinetic mechanism for CO, CH2O, and CH3OH combustion
Journal: Int. J. Chem. Kinet.
Volume: 39
Page(s): 109 - 136
Year: 2007
Reference type: Journal article
Squib: 2007LI/ZHA109-136
Reaction:
CO + ·OH → CO2 + H·
Reaction order:
2
Temperature:
850 - 950
K
Pressure: 1.52 - 6.08 bar
Rate expression:
1.76x10-14 [cm3/molecule s] (T/298 K)1.89 e4847 [J/mole]/RT
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Experimental procedure:
Stirred flow reactor(PSR etc.)
Excitation technique:
Thermal
Time resolution:
In both real time and by end product analysis
Analytical technique:
Fourier transform (FTIR)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 850 | 2.53E-13 |
| 875 | 2.62E-13 |
| 900 | 2.71E-13 |
| 925 | 2.81E-13 |
| 950 | 2.90E-13 |