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Title: Theoretical investigation of the gas-phase kinetics active during the GaN MOVPE
Journal: J. Phys. Chem. A
Volume: 111
Page(s): 4620 - 4631
Year: 2007
Reference type: Journal article
Squib: 2007MOS/CAV4620-4631
Reaction:
(CH3)2GaNHGa(CH3)NHGa(CH3)NH2 → cyc-Ga(CH3)NHGa(CH3)NHGa(CH3)NH + CH4
Reaction order:
1
Temperature:
1273 - 1273
K
Rate expression:
1.2x109 [s-1] (T/298 K)1.00 e-100416 [J/mole]/RT
Category: Theory
Data type:
Transition state theory
Pressure dependence:
Rate constant is high pressure limit
Comments:
Reaction potential energy surface was studied using quantum chemistry and rate constants were calculated using transition state theory. The exact temperature range of the modified Arrhenius expression is not given.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1273 | 3.88E5 |
| 1273 | 3.88E5 |