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Title: Experimental and theoretical study on the kinetics and mechanism of thermal decomposition of 1,2-dichloroethane
Journal: J. Iran. Chem. Soc.
Volume: 4
Page(s): 279 - 298
Year: 2007
Reference type: Journal article
Squib: 2007MOU/SAH279-298
Reaction:
CH2ClCH2Cl → CH2=CHCl + HCl
Reaction order:
1
Temperature:
849 - 1064
K
Pressure: 1.33E-2 - 0.40 bar
Rate expression:
4.2x1013 [s-1] e-235700 [J/mole]/RT
Category: Experiment
Data type:
High or low pressure extrapolation
Pressure dependence:
Rate constant is high pressure limit
Experimental procedure:
Stirred flow reactor(PSR etc.)
Excitation technique:
Thermal
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
Troe extrapolation of experimental pyrolysis data.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 849 | 1.32E-1 |
| 850 | 1.38E-1 |
| 875 | 3.57E-1 |
| 900 | 8.79E-1 |
| 925 | 2.06E0 |
| 950 | 4.61E0 |
| 975 | 9.91E0 |
| 1000 | 2.05E1 |
| 1025 | 4.09E1 |
| 1050 | 7.91E1 |
| 1064 | 1.13E2 |