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Title: Kinetic study of the reactions of Cl atoms with CF2CH2CH2OH, CF3CF2CH2OH, CHF2CF2CH2OH, and CF3CHFCF2CH2OH
Journal: J. Phys. Chem. A
Volume: 111
Page(s): 11608 - 11617
Year: 2007
Reference type: Journal article
Squib: 2007PAP/PAP11608-11617
Reaction:
CF3CHFCF2CH2OH + Cl → Products + HCl
Reaction order:
2
Temperature:
273 - 363
K
Pressure: 2.67E-3 bar
Rate expression:
6.18x10-12 [±8.4x10-13 cm3/molecule s] e-6119 [±349 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Discharge
Time resolution:
By end product analysis
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 273 | 4.17E-13 |
| 275 | 4.25E-13 |
| 300 | 5.32E-13 |
| 325 | 6.42E-13 |
| 350 | 7.55E-13 |
| 363 | 8.14E-13 |