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Title: High-temperature rate constants for CH3OH+Kr -> products, OH+CH3OH -> products, OH+(CH3)CO -> CH2COCH3+H2O, and OH+CH3 -> CH2+H2O
Journal: J. Phys. Chem. A
Volume: 111
Page(s): 3951 - 3958
Year: 2007
Reference type: Journal article
Squib: 2007SRI/SU3951-3958
Reaction:
CH3OH + Kr → CH2(1) + Kr + H2O
Reaction order:
2
Temperature:
1734 - 2287
K
Rate expression:
3.27x10-10 [cm3/molecule s] e-215727 [J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Shock tube
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 1734 | 1.04E-16 |
| 1750 | 1.19E-16 |
| 1800 | 1.80E-16 |
| 1850 | 2.65E-16 |
| 1900 | 3.84E-16 |
| 1950 | 5.44E-16 |
| 2000 | 7.59E-16 |
| 2050 | 1.04E-15 |
| 2100 | 1.41E-15 |
| 2150 | 1.88E-15 |
| 2200 | 2.47E-15 |
| 2250 | 3.21E-15 |
| 2287 | 3.87E-15 |