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Author(s):   Takahashi, K.;Iwasaki, E.;Matsumi, Y.;Wallington, T.J.
Title:   Pulsed laser photolysis vacuum UV laser-induced fluorescence kinetic study of the gas-phase reactions of Cl(2P3/2) atoms with C3 to C6 ketones
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   1271 - 1276
Year:   2007
Reference type:   Journal article
Squib:   2007TAK/IWA1271-1276

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2007TAK/IWA1271-1276   C2H5COCH3 + Cl → Products  295   4.08E-11              2
  2007TAK/IWA1271-1276   (CH3)2CO + Cl → Products  295   2.30E-12              2
  2007TAK/IWA1271-1276   n-C3H7C(O)CH3 + Cl → Products  295   1.23E-10              2
  2007TAK/IWA1271-1276   (C2H5)2CO + Cl → Products  295   8.87E-11              2
  2007TAK/IWA1271-1276   n-C4H9COCH3 + Cl → Products  295   2.08E-10              2
  2007TAK/IWA1271-1276   n-C3H7COC2H5 + Cl → Products  295   1.43E-10              2
  2007TAK/IWA1271-1276   Cyclopentanone + Cl → Products  295   1.16E-10              2

Search returned 7 records.