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Author(s):   Takahashi, K.;Iwasaki, E.;Matsumi, Y.;Wallington, T.J.
Title:   Pulsed laser photolysis vacuum UV laser-induced fluorescence kinetic study of the gas-phase reactions of Cl(2P3/2) atoms with C3 to C6 ketones
Journal:   J. Phys. Chem. A
Volume:   111
Page(s):   1271 - 1276
Year:   2007
Reference type:   Journal article
Squib:   2007TAK/IWA1271-1276

Reaction:   (CH3)2CO + Cl → Products
Reaction order:   2
Temperature:   295 K
Pressure:  8.80E-3 bar
Rate expression:   2.3x10-12 [±1.2x10-13 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   351-nm photolysis of Cl2 used as source of Cl atoms, whihc were detected by 134.72-nm radiation generated by four-wave frequency mixing.

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