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Title: Pulsed laser photolysis vacuum UV laser-induced fluorescence kinetic study of the gas-phase reactions of Cl(2P3/2) atoms with C3 to C6 ketones
Journal: J. Phys. Chem. A
Volume: 111
Page(s): 1271 - 1276
Year: 2007
Reference type: Journal article
Squib: 2007TAK/IWA1271-1276
Reaction:
(CH3)2CO + Cl → Products
Reaction order:
2
Temperature:
295
K
Pressure: 8.80E-3 bar
Rate expression:
2.3x10-12 [±1.2x10-13 cm3/molecule s]
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
Comments:
351-nm photolysis of Cl2 used as source of Cl atoms, whihc were detected by 134.72-nm radiation generated by four-wave frequency mixing.
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