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Title: Experimental and theoretical studies of rate coefficients for the reaction O(3P) plus C2H5OH at high temperatures
Journal: J. Phys. Chem. A
Volume: 111
Page(s): 6693 - 6703
Year: 2007
Reference type: Journal article
Squib: 2007WU/LEE6693-6703
Reaction:
O(3P) + C2H5OH → Products
Reaction order:
2
Temperature:
782 - 1410
K
Rate expression:
1.34x10-10 [±1.1x10-11 cm3/molecule s] e-25276 [±665 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Shock tube
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Other (direct)
Comments:
O atoms were measured via ARAS.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 782 | 2.75E-12 |
| 800 | 3.00E-12 |
| 850 | 3.75E-12 |
| 900 | 4.57E-12 |
| 950 | 5.46E-12 |
| 1000 | 6.41E-12 |
| 1050 | 7.41E-12 |
| 1100 | 8.45E-12 |
| 1150 | 9.53E-12 |
| 1200 | 1.06E-11 |
| 1250 | 1.18E-11 |
| 1300 | 1.29E-11 |
| 1350 | 1.41E-11 |
| 1400 | 1.53E-11 |
| 1410 | 1.55E-11 |