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Title: Multichannel reaction of C2Cl3+O2 studied by time-resolved Fourier transform infrared emission spectroscopy
Journal: J. Phys. Chem. A
Volume: 111
Page(s): 9606 - 9612
Year: 2007
Reference type: Journal article
Squib: 2007XIA/LIU9606-9612
Reaction:
O2 + CCl2=CCl → CO2 + ·CCl3
Reaction order:
2
Temperature:
298
K
Pressure: 1.00E-3 bar
Rate expression:
no rate data available
Category: Experiment
Data type:
Mechanistic information only
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
By end product analysis
Analytical technique:
Fourier transform (FTIR)
Comments:
Reaction products were detected and their vibrational excitation was analyzed. No rate constant values were obtained.
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