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Title: Thermal stability of carbonyl radicals - Part II. Reactions of methylglyoxyl and methylglyoxylperoxy radicals at 1 bar in the temperature range 275-311 K
Journal: Phys. Chem. Chem. Phys.
Volume: 10
Page(s): 1799 - 1808
Year: 2008
Reference type: Journal article
Squib: 2008JAG/ZAB1799-1808
Reaction:
CH3C(O)C(O)O2 → CO2 + H2C=C=O + ·OH
Reaction order:
1
Temperature:
275 - 311
K
Pressure: 1.00 bar
Rate expression:
1.0x102 [s-1]
Category: Experiment
Data type:
Estimated: thermochemical, kinetic, or other
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
In real time
Analytical technique:
Fourier transform (FTIR)
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