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Home ©NIST, 2013 Accessibility information |
Title: Rate constant of the gas-phase reaction between Fe atoms and CO2
Journal: Kinet. Catal.
Volume: 49
Page(s): 607 - 609
Year: 2008
Reference type: Journal article
Squib: 2008SMI607-609
Reaction:
CO + FeO → CO2 + Fe
Reaction order:
2
Temperature:
1180 - 2380
K
Pressure: 4.22E13 - 6.02E13 bar
Rate expression:
7.66x10-13 [cm3/molecule s] (T/298 K)0.57 e-4074 [±9146 J/mole]/RT
Uncertainty:
2.0
Category: Experiment
Data type:
Derived from detailed balance/reverse rate
Experimental procedure:
Shock tube
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 1180 | 1.11E-12 |
| 1200 | 1.13E-12 |
| 1300 | 1.22E-12 |
| 1400 | 1.30E-12 |
| 1500 | 1.39E-12 |
| 1600 | 1.47E-12 |
| 1700 | 1.55E-12 |
| 1800 | 1.63E-12 |
| 1900 | 1.70E-12 |
| 2000 | 1.78E-12 |
| 2100 | 1.85E-12 |
| 2200 | 1.92E-12 |
| 2300 | 1.98E-12 |
| 2380 | 2.04E-12 |