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Accessibility information
Author(s):   Vasudevan, V.; Cook, R.D.; Hanson, R.K.; Bowman, C.T.; Golden, D.M.
Title:   High-temperature shock tube study of the reactions CH3+OH -> products and CH3OH+Ar -> products
Journal:   Int. J. Chem. Kinet.
Volume:   40
Page(s):   488 - 495
Year:   2008
Reference type:   Journal article
Squib:   2008VAS/COO488-495

Reaction:   CH3OH·CH3 + ·OH
Reaction order:   2
Temperature:   1904 - 2298 K
Pressure:  1.32 bar
Rate expression:   9.33x10-9 [cm3/molecule s] e-256560 [J/mole]/RT
Category:  Experiment
Data type:   Experimental value and limited review
Experimental procedure:   Shock tube
Analytical technique:   Vis-UV absorption
Comments:   CH3 radicals were generated by shock-heating methyl iodide.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1904 8.54E-16
1925 1.02E-15
1950 1.25E-15
1975 1.53E-15
2000 1.86E-15
2025 2.25E-15
2050 2.71E-15
2075 3.25E-15
2100 3.88E-15
2125 4.61E-15
2150 5.46E-15
2175 6.44E-15
2200 7.56E-15
2225 8.85E-15
2250 1.03E-14
2275 1.20E-14
2298 1.38E-14