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Title: Experimental and ab initio dynamical investigations of the kinetics and intramolecular energy transfer mechanisms for the OH+1,3-butadiene reaction between 263 and 423 K at low pressure
Journal: J. Phys. Chem. A
Volume: 112
Page(s): 7227 - 7237
Year: 2008
Reference type: Journal article
Squib: 2008VIM/PAC7227-7237
Reaction:
1,3-Butadiene + ·OH → 1,3-Butadiene-OH adduct
Reaction order:
2
Temperature:
300
K
Pressure: 2.67E-3 - 6.67E-3 bar
Rate expression:
6.98x10-11 [±2.8x10-12 cm3/molecule s]
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Discharge
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
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