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Author(s):   Vimal, D.; Pacheco, A.B.; Iyengar, S.S.; Stevens, P.S.
Title:   Experimental and ab initio dynamical investigations of the kinetics and intramolecular energy transfer mechanisms for the OH+1,3-butadiene reaction between 263 and 423 K at low pressure
Journal:   J. Phys. Chem. A
Volume:   112
Page(s):   7227 - 7237
Year:   2008
Reference type:   Journal article
Squib:   2008VIM/PAC7227-7237

Reaction:   1,3-Butadiene + ·OH → 1,3-Butadiene-OH adduct
Reaction order:   2
Temperature:   300 K
Pressure:  2.67E-3 - 6.67E-3 bar
Rate expression:   6.98x10-11 [±2.8x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Discharge
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

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