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Author(s):   Yasunaga, K.; Kuraguchi, Y.; Hidaka, Y.; Takahashi, O.; Yamada, H.; Koike, T.
Title:   Kinetic and modeling studies on ETBE pyrolysis behind reflected shock waves
Journal:   Chem. Phys. Lett.
Volume:   451
Page(s):   192 - 197
Year:   2008
Reference type:   Journal article
Squib:   2008YAS/KUR192-197

Reaction:   tert-C4H9OC2H5C2H5OH + iso-C4H8
Reaction order:   1
Temperature:   1000 - 1500 K
Pressure:  1.01 - 9.12 bar
Rate expression:   1.7x1014 [s-1] e-254000 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is high pressure limit
Experimental procedure:   Shock tube
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 9.19E0
1050 3.93E1
1100 1.48E2
1150 4.94E2
1200 1.49E3
1250 4.14E3
1300 1.06E4
1350 2.53E4
1400 5.67E4
1450 1.20E5
1500 2.43E5