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Author(s):   Hurley, M.D.; Wallington, T.J.; Lauirsen, L.; Javadi, M.S.; Nielsen, O.J.; Yamanaka, T.; Kawasaki, M.
Title:   Atmospheric Chemistry of n-Butanol: Kinetics, Mechanisms, and Products of Cl Atom and OH Radical Initiated Oxidation in the Presence and Absence of NOx.
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   7011 - 7020
Year:   2009
Reference type:   Journal article
Squib:   2009HUR/WAL7011-7020

Reaction:   n-C4H9OH + Cl → Products
Reaction order:   2
Reference reaction:   C2H4 + Cl → Products
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   2.19x10-10 [±3.2x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In both real time and by end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Indicated error limits are two least-squares standard deviations.

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