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Title: Atmospheric Chemistry of n-Butanol: Kinetics, Mechanisms, and Products of Cl Atom and OH Radical Initiated Oxidation in the Presence and Absence of NOx.
Journal: J. Phys. Chem. A
Volume: 113
Page(s): 7011 - 7020
Year: 2009
Reference type: Journal article
Squib: 2009HUR/WAL7011-7020
Reaction:
n-C4H9OH + ·OH → Products
Reaction order:
2
Temperature:
296
K
Pressure: 0.93 bar
Rate expression:
8.86x10-12 [±8.5x10-13 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
In both real time and by end product analysis
Analytical technique:
Fourier transform (FTIR)
Comments:
The rate constant value is the average of the individual determinations using two reference compounds (acetylene and ethylene). The reported error limits encompass the extremes of the individual determinations.
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