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Author(s):   Pokidova, T.S.; Denisov, E.T.; Shestakov, A.F.
Title:   Kinetic parameters and geometry of the transition state in the unimolecular degradation of alcohols
Journal:   Petrol. Chem.
Volume:   49
Page(s):   343 - 353
Year:   2009
Reference type:   Journal article
Squib:   2009POK/DEN343-353

Reaction:   (CH3)2CO + 1-C4H8 → CH3CH=CHCH2C(CH3)2OH
Reaction order:   2
Temperature:   650 K
Rate expression:   1.31x10-24 [cm3/molecule s]
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Pressure dependence:   Rate constant is high pressure limit
Comments:   Rate constants were calculated for 13 alcohol formation reactions using the method of crossing parabolas.

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