NIST Chemical Kinetics Database

Author(s):   Sivaramakrishnan, R.; Michael, J.V.
Title:   Rate Constants for OH with Selected Large Alkanes: Shock-Tube Measurements and an Improved Group Scheme
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   5047 - 5060
Year:   2009
Reference type:   Journal article
Squib:   2009SIV/MIC5047-5060

Reaction:   n-C₄H₁₀ + ·OH → Products
Reaction order:   2
Temperature:   298 - 2000 K
Rate expression:   3.79x10^-12 [cm³/molecule s] (T/298 K)^1.48 e^{-1156 [J/mole]/RT}
Category: Theory
Data type:   Estimated: thermochemical, kinetic, or other
Comments:   Rate constants calculated using a group reactivity scheme devised in this work.

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [cm³/molecule s]
298	2.38E-12
300	2.41E-12
400	4.14E-12
500	6.16E-12
600	8.44E-12
700	1.10E-11
800	1.37E-11
900	1.66E-11
1000	1.97E-11
1100	2.29E-11
1200	2.64E-11
1300	2.99E-11
1400	3.36E-11
1500	3.75E-11
1600	4.15E-11
1700	4.56E-11
1800	4.98E-11
1900	5.42E-11
2000	5.86E-11