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©NIST, 2013
Accessibility information
Author(s):   Sivaramakrishnan, R.; Michael, J.V.
Title:   Rate Constants for OH with Selected Large Alkanes: Shock-Tube Measurements and an Improved Group Scheme
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   5047 - 5060
Year:   2009
Reference type:   Journal article
Squib:   2009SIV/MIC5047-5060

Reaction:   n-C4H10 + ·OH → Products
Reaction order:   2
Temperature:   298 - 2000 K
Rate expression:   3.79x10-12 [cm3/molecule s] (T/298 K)1.48 e-1156 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Comments:   Rate constants calculated using a group reactivity scheme devised in this work.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.38E-12
300 2.41E-12
400 4.14E-12
500 6.16E-12
600 8.44E-12
700 1.10E-11
800 1.37E-11
900 1.66E-11
1000 1.97E-11
1100 2.29E-11
1200 2.64E-11
1300 2.99E-11
1400 3.36E-11
1500 3.75E-11
1600 4.15E-11
1700 4.56E-11
1800 4.98E-11
1900 5.42E-11
2000 5.86E-11