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Author(s):   Teruel, M.A.; Achad, M.; Blanco, M.B.
Title:   Kinetic study of the reactions of Cl atoms with unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs)
Journal:   Chem. Phys. Lett.
Volume:   479
Page(s):   25 - 29
Year:   2009
Reference type:   Journal article
Squib:   2009TER/ACH25-29

Reaction:   CH2=CHCOOC2H5 + Cl → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   2.53x10-10 [±4.6x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   CH2CCl2 and CH2CHCN were used as reference compounds. Error limits are twice the standard deviations from least-squares fits with additional contribution from the uncertainties in the reference rate constants.

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