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Home ©NIST, 2013 Accessibility information |
Title: Spectrokinetic Study of the Reaction System of 2NO 2<-> N2O4 with Butanols Between 320-358 K in the Gas Phase
Journal: Pol. J. Chem.
Volume: 83
Page(s): 131 - 143
Year: 2009
Reference type: Journal article
Squib: 2009WOJ/JOD131-143
Reaction:
n-C4H9OH + N2O4 → n-C4H9ONO + HNO3
Reaction order:
2
Temperature:
298
K
Pressure: 0.25 - 0.50 bar
Rate expression:
3.9x10-18 [±1.0x10-18 cm3/molecule s]
Category: Experiment
Data type:
Estimated: thermochemical, kinetic, or other
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
Comments:
Reaction was studied in the 320 - 358 K temperature range. The value of the rate constant reported here is an extrapolation to 298 K reported by the authors.
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