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Title: Kinetics of the reactions of chlorine atoms with a series of acetates
Journal: Chem. Phys. Lett.
Volume: 474
Page(s): 268 - 272
Year: 2009
Reference type: Journal article
Squib: 2009XIN/TAK268-272
Reaction:
CH3COOC2H5 + Cl → Products
Reaction order:
2
Temperature:
296
K
Pressure: 0.93 bar
Rate expression:
1.76x10-11 [±2.6x10-12 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Fourier transform (FTIR)
Comments:
Acetylene and ethylene were used as reference compounds. Quoted rate constant value is an average of the two determinations with uncertainty which encompasses the extremes of the individual determinations.
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