Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Xing, J.H.; Takahashi, K.; Hurley, M.D.; Wallington, T.J.
Title:   Kinetics of the reactions of chlorine atoms with a series of acetates
Journal:   Chem. Phys. Lett.
Volume:   474
Page(s):   268 - 272
Year:   2009
Reference type:   Journal article
Squib:   2009XIN/TAK268-272

Reaction:   CH3COOC2H5 + Cl → Products
Reaction order:   2
Temperature:   295 K
Pressure:  2.53E-3 - 8.80E-3 bar
Rate expression:   1.76x10-11 [±1.1x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Quoted uncertainty includes two standard deviations from the least-squares fit analysis and systematic uncertainty associated with the reactant concentration.

View full bibliographic record.