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Title: Atmospheric chemistry of CF3CF2H and CF3CF2CF2CF2H: Kinetics and products of gas-phase reactions with Cl atoms and OH radicals, infrared spectra, and formation of perfluorocarboxylic acids
Journal: Chem. Phys. Lett.
Volume: 473
Page(s): 251 - 256
Year: 2009
Reference type: Journal article
Squib: 2009YOU/HUR251-256
Reaction:
C2F5H + ·OH → Products
Reaction order:
2
Reference reaction:
C2H4 + ·OH → Products
Temperature:
296
K
Pressure: 0.93 bar
Rate expression:
1.96x10-15 [±2.5x10-16 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Fourier transform (FTIR)
Comments:
Quoted uncertainties include two standard deviations from the linear least squares regression analysis and uncertainties associated with the IR analyses.
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