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Author(s):   Trevitt, A.J.; Goulay, F.; Taatjes, C.A.; Osborn, D.L.; Leone, S.R.
Title:   Reactions of the CN Radical with Benzene and Toluene: Product Detection and Low-Temperature Kinetics
Journal:   J. Phys. Chem. A
Volume:   114
Page(s):   1749 - 1755
Year:   2010
Reference type:   Journal article
Squib:   2010TRE/GOU1749-1755

Reaction:   CN + Toluene → Products
Reaction order:   2
Temperature:   105 K
Pressure:  2.40E11 bar
Rate expression:   1.3x10-10 [±3.0x10-11 cm3/molecule s]
Uncertainty:   1.2
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Laval nozzle
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Error bars of 20% are ascribed to the measured rate coefficients to take into account statistical and systematic uncertainties. The only product detected in separate VUV photoionization mass spectrometry experiments is cyanotoluene, NCC6H4CH3.

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