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CH3OH + Cl(·)CH2OH + HCl

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
Review
  2001ATK/BAU1-56   200 - 580   5.50E-11           5.50E-11  2
  1997DEM/SAN1-266   200 - 300   5.40E-11           5.40E-11  2
  1997ATK/BAU521-1011   200 - 573   5.50E-11           5.50E-11  2
  1994DEM/SAN   200 - 300   5.40E-11           5.40E-11  2
  1992ATK/BAU1125-1568   200 - 500   5.30E-11           5.30E-11  2
 
Experiment
  2004SEA/ORL2224-2229   243   5.08E-11              2
  2004SEA/ORL2224-2229   298   5.83E-11           5.83E-11  2
  2004SEA/ORL2224-2229   298   5.38E-11           5.38E-11  2
  1999TYN/ORL776-784   295   5.40E-11              2
  1993DOB/OTT877-884   298   6.14E-11           6.14E-11  2
  1990NEL/RAT1111-1126   298   4.78E-11           4.78E-11  2
  1990LIG/VEY708-714   248 - 573   5.30E-11           5.30E-11  2
  1988WAL/SKE867   295   4.57E-11              2
  1988PAG/MUN375   298   6.14E-11           6.14E-11  2
  1979MIC/NAV3652   200 - 500   6.33E-11           6.33E-11  2
  1994DOB/BER775-781   298   0.93           0.93  2
  Reference reaction:  CH3OH + Cl → Products 2
  1990LIG/VEY708-714   248 - 573   4.58       -1.16E04   503  2
  Reference reaction:  CH4 + Cl·CH3 + HCl 2
  1988WAL/SKE867   295   0.80              2
  Reference reaction:  C2H6 + Cl·C2H5 + HCl 2
 
Theory
    2004RUD/MUR186-198                      2
  1998JOD/RAY9230-9243   300 - 1000   6.60E-11       -191      2
  1992SEN/QUA10837-10842   300 - 400   3.72E-11       -1563      2
 
Other
    2004BEC/CAM4231-4239                      2

Search returned 22 records.