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CHCl3 + ·OH·CCl3 + H2O

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
Review
  2001ATK/BAU1-56   240 - 300   9.30E-13       5488   1.02E-13  2
  1997DEM/SAN1-266   200 - 300   2.01E-12       7483   9.80E-14  2
  1997ATK/BAU521-1011   240 - 300   9.30E-13       5488   1.02E-13  2
  1994DEM/SAN   200 - 300   2.01E-12       7483   9.80E-14  2
  1992ATK/BAU1125-1568   240 - 300   3.30E-12       8564   1.04E-13  2
  1991COH/WES1211-1311   250 - 2000   1.43E-13   2.80   831   1.02E-13  2
  1989ATK/BAU881-1097   240 - 300   3.30E-12       8564   1.04E-13  2
  1986ATK69   240 - 500   5.60E-13   2.00   4190   1.03E-13  2
  1981BAU/DUX   240 - 380   4.68E-12       9395   1.06E-13  2
 
Experiment
  1998KOW/JOW75-78   298   1.68E-13           1.68E-13  2
  1994HSU/DEM805-808   283 - 357   1.20E-12       6485   8.76E-14  2
  1993TAY/JIA9-23   295 - 774   2.71E-13   1.52   2170   1.13E-13  2
  1989TAY/DAN829-846   295 - 775   1.45E-13   2.78   790   1.05E-13  2
  1986KLO/FRA57-62   300   3.01E-13              2
  1982JEO/KAU1808   249 - 487   5.65E-12       9811   1.08E-13  2
  1976HOW/EVE197   296   1.01E-13              2
  1976DAV/MAC1268   245 - 375   4.68E-12       9395   1.06E-13  2
  1976COX/DER305   298   1.68E-13           1.68E-13  2
  1994HSU/DEM805-808   288 - 357   0.52       -4116   2.74  2
  Reference reaction:  CH3CHF2 + ·OH → Other Products + H2O 2
 
Theory
  2000LOU/GON8773-8778   250 - 400   9.00E-13       2868   2.83E-13  2
  1993CHI/PIA241-250   298   8.32E-14           8.32E-14  2
  1987COH/BEN171-175   290 - 306   1.22E-12       4656   1.86E-13  2
  1987COH/BEN162-170   298 - 2000   1.76E-13   1.70   1413   9.95E-14  2

Search returned 23 records.