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CH4 + ·F·CH3 + HF

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
Review
  2001ATK/BAU1-56   180 - 410   1.30E-10       1788   6.32E-11  2
  1998PER390-394   184 - 406   1.28E-10       1788   6.22E-11  2
  1997DEM/SAN1-266   200 - 300   1.60E-10       2162   6.69E-11  2
  1997ATK/BAU521-1011   250 - 450   3.01E-10       3326   7.85E-11  2
  1994DEM/SAN   200 - 300   3.01E-10       3326   7.85E-11  2
  1992ATK/BAU1125-1568   250 - 450   3.01E-10       3326   7.85E-11  2
  1989ATK/BAU881-1097   250 - 450   3.01E-10       3326   7.85E-11  2
  1981BAU/DUX   300   6.64E-11              2
 
Experiment
  1996PER689-693   184 - 406   1.64E-10       2203   6.75E-11  2
  1995MOO/SMI3041-3044   298   4.70E-11           4.70E-11  2
  1994MOO/SMI813-825   139 - 294   3.35E-11       -1031      2
  1989WOR/HEY1132-1136   298   6.59E-11           6.59E-11  2
  1988PAG/MUN375   298   6.64E-11           6.64E-11  2
  1983CLY/HOD351   298   6.59E-11           6.59E-11  2
  1982FAS/NOG411-414   298   5.71E-11           5.71E-11  2
  1978CLY/NIP367   298   7.51E-11           7.51E-11  2
  1973POL/JON2041-2046   298   >9.96E-11           9.96E-11  2
  1973PEA/COW879   298   3.82E-11           3.82E-11  2
  1973CLY/MCK3596   298   5.99E-11           5.99E-11  2
  1972KOM/WAN560   298   7.14E-11           7.14E-11  2
  1971WAG/WAR169   250 - 312   5.48E-10       4806   7.88E-11  2
  1960FET/KNO1064   198 - 351   1.63E-10       5055   2.11E-11  2
  2006PER251-254   183 - 298   0.99       -831      2
  Reference reaction:  CD4 + ·FCD3 + DF 2
  1997PLA/SEH2855-2863   296   0.28              2
  Reference reaction:  1,4-Dioxane + ·F1,4-Dioxan-2-yl + HF 2
  1996PER689-693   184 - 406   1.21       -3492   4.95  2
  Reference reaction:  D2 + ·FDF + D 2
  1996PER689-693   184 - 406   1.16       -1954   2.55  2
  Reference reaction:  H2 + ·FHF + 2
  1995MOO/SMI3041-3044   298   6.70           6.70  2
  Reference reaction:  HCl + ·FHF + Cl 2
  1994SEH/SEH6731-6739   298   25.10           25.10  2
  Reference reaction:  O2 + ·FO2F 2
  1991ANA/BEV2325-2329   294   3.20              2
  Reference reaction:  H2O + ·F·OH + HF 2
  1975MAN/GRA39   303   2.58              2
  Reference reaction:  H2 + ·FHF + 2
  1973WIL/ROW301-307   298   2.90           2.90  2
  Reference reaction:  H2 + ·FHF + 2
  1973WIL/ROW301-307   298   0.41           0.41  2
  Reference reaction:  C2H2 + ·F → CHF=CH· 2
  1972FOO/REI1131   183 - 348   1.00       -956   1.47  2
  Reference reaction:  CD4 + ·FCD3 + DF 2
  1972FOO/REI1131   183 - 348   1.26       -3002   4.23  2
  Reference reaction:  D2 + ·FDF + D 2
  1971WIL/ROW2709   283   0.43              2
  Reference reaction:  C2H2 + ·F → CHF=CH· 2
  1971FOO/REI3513   273 - 358   4.20       5729   0.42  2
  Reference reaction:  C2H6 + ·F·C2H5 + HF 2
  1970KAP/MAR669   223 - 353   3.58       -4099   18.72  2
  Reference reaction:  D2 + ·FDF + D 2
  1959MER/PRI1468   298 - 423   1.05       2087   0.45  2
  Reference reaction:  H2 + ·FHF + 2
 
Theory
    2007ESP/BRA2761-2771   180 - 500               0.00E00  2
    2005ROB/MAC27-34   200 - 2000               0.00E00  2
    2005RAN/NAV1441-1448   180 - 500               0.00E00  2
    2004TRO/MIL5181-5191   150 - 500               0.00E00  2
  2004TRO/MIL5181-5191   298   4.37E-11           4.37E-11  2
  1985LER/SAN1447-1456   690 - 710   1.99E-10       -665      2
    2007ESP/BRA2761-2771   180 - 500               0.00E00  2
  Reference reaction:  CD4 + ·FCD3 + HF 2
    1996COR/ESP3160-3167                       
    1996COR/ESP3152-3159                       

Search returned 47 records.