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Author(s):   Richard, C.; Boiveaut, A.; Martin, R.
Title:   H2S-Promoted Therm al Isomerization of Butene-2 cis to Butene-1 or Butene-2 trans around 500oC
Journal:   Int. J. Chem. Kinet.
Volume:   12
Year:   1980
Reference type:   Journal article
Squib:   1980RIC/BOI921

Reaction:   (Z)-2-C4H8 + ·CH2CH=CHCH31-C4H8 + ·CH2CH=CHCH3
Reaction order:   2
Temperature:   750 - 816 K
Pressure:  1.33E-2 - 0.13 bar
Rate expression:   6.61x10-11 [cm3/molecule s] e-66100 [J/mole]/RT
Bath gas:   (Z)-2-C4H8
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
750 1.65E-15
775 2.32E-15
800 3.19E-15
816 3.88E-15