Author(s):   Timonen, R.S.; Russell, J.J.; Gutman, D.
Title:   Kinetics of the reactions of halogenated methyl radicals (CF₃, CF₂Cl, CFCl₂, and CCl₃) with molecular chlorine
Journal:   Int. J. Chem. Kinet.
Volume:   18
Page(s):   1193 - 1204
Year:   1986
Reference type:   Journal article
Squib:   1986TIM/RUS1193-1204

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
1986TIM/RUS1193-1204	·CClF₂ + Cl₂ → CF₂Cl₂ + ·Cl	376 - 626	1.29E-12	7999	2
1986TIM/RUS1193-1204	·CCl₂F + Cl₂ → CFCl₃ + ·Cl	435 - 693	1.38E-12	1.40E04	2
1986TIM/RUS1193-1204	·CF₃ + Cl₂ → CF₃Cl + ·Cl	487 - 693	4.47E-12	1.50E04	2
1986TIM/RUS1193-1204	·CCl₃ + Cl₂ → CCl₄ + ·Cl	690 - 700	6.77E-13	2.20E04	2

Search returned 4 records.