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 Author(s):   Westmoreland, P.R.; Dean, A.M.; Howard, J.B.; Longwell, J.P.
Title:   Forming benzene in flames by chemically activated isomerization
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   8171 - 8180
Year:   1989
Reference type:   Journal article
Squib:   1989WES/DEA8171-8180

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1989WES/DEA8171-8180   C2H2 + HCCCHCH· → Products  1000 - 1700   8.10E-14   1.65   1.05E04      2
  1989WES/DEA8171-8180   C2H2 + HCCCHCH· → Benzyne + H·  400 - 1600   5.38E-19   6.48   2.78E04      2
  1989WES/DEA8171-8180   C2H2 + HCCCHCH· → Phenyl  400 - 1600   8.67E-12   -0.86   2.67E04      2
  1989WES/DEA8171-8180   C2H2 + HCCCHCH· → H· + (Z)-HC≡CCH=CHC≡CH  400 - 1600   3.12E-17   5.59   2.52E04      2
  1989WES/DEA8171-8180   C2H2 + HCCCHCH· → CH=CHCH=CHC≡CH  400 - 1600   1.88E-12   -1.51   2.02E04      2
  1989WES/DEA8171-8180   C2H2 + CH2=CHCH=CH· → Products  1000 - 1700   7.77E-14   1.79   9395      2
  1989WES/DEA8171-8180   C2H2 + CH2=CHCH=CH· → Benzene + H·  400 - 1600   3.29E-13   1.18   1.56E04      2
  1989WES/DEA8171-8180   C2H2 + CH2=CHCH=CH· → 1,3-Hexadien-5-yne + H·  400 - 1600   7.69E-20   7.73   1.05E04      2
  1989WES/DEA8171-8180   C2H2 + CH2=CHCH=CH· → 2,4-Cyclohexadien-1-yl  400 - 1600   1.16E-11   -3.64   2.62E04      2
  1989WES/DEA8171-8180   C2H2 + CH2=CHCH=CH· → CH2=CHCH=CHCH=CH·  400 - 1600   4.63E-13   -1.38   1.66E04      2
  1989WES/DEA8171-8180   1,3-Butadiene + C2H3 → Adduct  400 - 1600   9.30E-13   -0.17   1.36E04      2
  1989WES/DEA8171-8180   1,3-Butadiene + C2H3 → Products  1000 - 1700   6.46E-14   1.31   5729      2
  1989WES/DEA8171-8180   1,3-Butadiene + C2H3 → 1,3-Cyclohexadiene + H·  400 - 1600   4.45E-19   6.39   1.02E04      2
  1989WES/DEA8171-8180   1,3-Butadiene + C2H3 → (Z)-CH2=CHCH=CHCH=CH2 + H·  400 - 1600   1.78E-18   8.20   2.63E04      2
  1989WES/DEA8171-8180   1,3-Butadiene + C2H3 → 3-Cyclohexenyl  400 - 1600   5.36E-14   -1.35   1.67E04      2
  1989WES/DEA8171-8180   ·CH2CH=CH2 + ·CH2CH=CH2 → 1,5-Hexadiene  1000 - 1700   1.41E-11              2
  1989WES/DEA8171-8180   C2H3 + CH2=CHCH=CH· → Products  1000 - 1700   2.82E-11              2
  1989WES/DEA8171-8180   C2H3 + CH2=CHCH=CH· → Benzene + H2  400 - 1600   9.48E-20   7.07   -1.51E04      2
  1989WES/DEA8171-8180   C2H3 + CH2=CHCH=CH· → 1,3-Cyclohexadiene  400 - 1600   2.54E-13   -1.11   3434      2
  1989WES/DEA8171-8180   C2H3 + CH2=CHCH=CH· → (Z)-CH2=CHCH=CHCH=CH2  400 - 1600   1.62E-11   -0.08   416      2
  1989WES/DEA8171-8180   C2H3 + CH2=CHCH=CH· → H· + CH2=CHCH=CHCH=CH·  400 - 1600   5.68E-27   16.20   -715      2
Search returned 21 records.