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Author(s):   Reyes, A.; Dominguez, R.M.; Tosta, M.; Herize, A.; Chuchani, G.
Title:   Kinetics of the gas-phase homogeneous unimolecular elimination of selected ethyl esters of 2-oxo-carboxylic acids
Journal:   J. Phys. Org. Chem.
Volume:   24
Page(s):   74 - 82
Year:   2011
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2011REY/DOM74-82

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2011REY/DOM74-82   ClC(O)C(O)OCH2CH3 → ClC(O)OCH2CH3 + CO  543 - 593   1.66E13       1.80E05      1
  2011REY/DOM74-82   Ethyl 1-Piperidineglyoxylate → Products  669 - 689   1.66E12       1.93E05      1
  2011REY/DOM74-82   Ethyl 1-Piperidineglyoxylate → C2H4 + CO2 + 1-Piperidinecarboxaldehyde  669 - 689   1.00E12       1.91E05      1
  2011REY/DOM74-82   Ethyl 1-Piperidineglyoxylate → CO + Ethyl 1-piperidinecarboxylate  669 - 689   3.98E12       2.11E05      1
  2011REY/DOM74-82   C6H5COC(O)OC2H5 → Products  643 - 672   1.74E13       2.06E05      1
  2011REY/DOM74-82   C6H5COC(O)OC2H5 → C2H4 + Benzaldehyde + CO2  643 - 672   7.76E12       2.04E05      1
  2011REY/DOM74-82   C6H5COC(O)OC2H5 → Ethyl benzoate + CO  643 - 672   2.45E13       2.13E05      1
Search returned 7 records.