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Author(s):   Orlando, J.J.; Piety, C.A.; Nicovich, J.M.; McKee, M.L.; Wine, P.H.
Title:   Rates and mechanisms for the reactions of chlorine atoms with iodoethane and 2-iodopropane
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   6659 - 6675
Year:   2005
Reference type:   Journal article
Squib:   2005ORL/PIE6659-6675

Reaction:   iso-C3H7I + ·Cliso-C3H7Cl + I
Reaction order:   2
Temperature:   298 K
Pressure:  5.33E-2 - 0.96 bar
Rate expression:   3.0x10-12 [cm3/molecule s]
Rate constant is an upper limit.
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)

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