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Author(s):   Oehlschlaeger, M.A.; Davidson, D.F.; Hanson, R.K.
Title:   High-temperature thermal decomposition of isobutane and n-butane behind shock waves
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   4247 - 4253
Year:   2004
Reference type:   Journal article
Squib:   2004OEH/DAV4247-4253

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
    2004OEH/DAV4247-4253   iso-C4H102-C3H7 + ·CH3  1310 - 1551                  1
    2004OEH/DAV4247-4253   1-C4H10·C2H5 + ·C2H5  1297 - 1601                  1
    2004OEH/DAV4247-4253   1-C4H101-C3H7 + ·CH3  1297 - 1601                  1
  2004OEH/DAV4247-4253   iso-C4H102-C3H7 + ·CH3  1320 - 1560   4.83E16       3.34E05      1
  2004OEH/DAV4247-4253   iso-C4H102-C3H7 + ·CH3  1320 - 1560   4.00E-05       2.20E05      2
  2004OEH/DAV4247-4253   1-C4H101-C3H7 + ·CH3  1320 - 1600   8.87E-07       1.80E05      2
  2004OEH/DAV4247-4253   1-C4H101-C3H7 + ·CH3  1320 - 1600   4.28E14       2.93E05      1
  2004OEH/DAV4247-4253   1-C4H10·C2H5 + ·C2H5  1320 - 1600   2.72E15       3.16E05      1
  2004OEH/DAV4247-4253   1-C4H10·C2H5 + ·C2H5  1320 - 1600   7.84E-06       2.07E05      2

Search returned 9 records.