Author(s):   Sahetchian, K.A.; Rigny, R.; Blin, N.; Heiss, A.
Title:   Homogeneous decomposition of dialkylperoxides in oxygen
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   83
Page(s):
Year:   1987
Reference type:   Journal article
Squib:   1987SAH/RIG2035

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Plot		Squib		Reaction		Temp [K]		A		n		Ea [J/mole]		k(298.00 K)		Order
		1987SAH/RIG2035		(n-C₄H₉)-OO-(n-C₄H₉) → CH₃CH₂CH₂CH₂O· + CH₃CH₂CH₂CH₂O·		473 - 513		1.05E16				1.60E05				1
		1987SAH/RIG2035		(n-C₇H₁₅)-O-O-(n-C₇H₁₅) → Products		423 - 483		1.00E15				1.53E05				1

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