Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Lockhart, J.; Blitz, M.; Heard, D.; Seakins, P.; Shannon, R.
Title:   Kinetic Study of the OH plus Glyoxal Reaction: Experimental Evidence and Quantification of Direct OH Recycling
Journal:   J. Phys. Chem. A
Volume:   117
Page(s):   11027 - 11037
Year:   2013
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2013LOC/BLI11027-11037

Reaction:   (CHO)2 + ·OH → Products
Reaction order:   2
Temperature:   250 K
Pressure:  6.67E-3 - 0.11 bar
Rate expression:   1.22x10-11 [±1.6x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Errors represent a combination of statistical errors at the 2σ level and estimates of systematic errors.

View full bibliographic record.