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 Author(s):   Sugawara, K.; Nakanaga, T.; Takeo, H.; Matsumura, C.
Title:   Reactions of CF2 carbene with Br2, Cl2 and H2 studied by means of CO2 laser photolysis and infrared diode laser spectroscopy
Journal:   Chem. Phys. Lett.
Volume:   134
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987SUG/NAK347

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1987SUG/NAK347   H2 + ·CF2 → CH2F2  550   <1.00E-16              2
  1987SUG/NAK347   ·CF2 + Br2 → CF2Br2  550   2.71E-15              2
  1987SUG/NAK347   ·CF2 + Cl2 → CF2Cl2  550   3.50E-15              2
Search returned 3 records.