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Author(s):   Sanders, W.A.; Lin, M.C.
Title:   Kinetics and mechanism of reactions of NF2 with olefins. Reinterpretation of existing data and estimation of C-N bond energies of alkyldifluoroamines
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   83
Year:   1987
Reference type:   Journal article
Squib:   1987SAN/LIN905

Reaction:   CH2=CHBr + NF2 → CH2CH(NF2)Br
Reaction order:   2
Temperature:   330 - 430 K
Pressure:  4.00E-2 - 0.97 bar
Rate expression:   1.99x10-14 [cm3/molecule s] e-58534 [J/mole]/RT
Bath gas:   C3H8
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
330 1.08E-23
350 3.66E-23
375 1.40E-22
400 4.53E-22
425 1.27E-21
430 1.55E-21