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Title: Kinetics and mechanism of reactions of NF2 with olefins. Reinterpretation of existing data and estimation of C-N bond energies of alkyldifluoroamines
Journal: J. Chem. Soc. Faraday Trans. 2
Volume: 83
Page(s):
Year: 1987
Reference type: Journal article
Squib: 1987SAN/LIN905
Reaction:
1-C4H8 + NF2 → C2H5CHCH2NF2
Reaction order:
2
Temperature:
330 - 430
K
Pressure: 4.00E-2 - 0.97 bar
Rate expression:
3.47x10-14 [cm3/molecule s] e-58534 [J/mole]/RT
Bath gas:
C3H8
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 330 | 1.89E-23 |
| 350 | 6.38E-23 |
| 375 | 2.44E-22 |
| 400 | 7.89E-22 |
| 425 | 2.22E-21 |
| 430 | 2.69E-21 |