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Applied Chemicals and Materials Division

Author(s):   Tsang, W.
Title:   Chemical kinetic data base for combustion chemistry. Part 4. Isobutane
Journal:   J. Phys. Chem. Ref. Data
Volume:   19
Page(s):   1 - 68
Year:   1990
Reference type:   Journal article
Squib:   1990TSA1-68

Reaction:   tert-C4H9Isobutene +
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   8.3x1013 [s-1] e-159638 [J/mole]/RT
Uncertainty:   3.0
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 1.33E-14
400 1.18E-7
500 1.75E-3
600 1.05E0
700 1.02E2
800 3.13E3
900 4.51E4
1000 3.81E5
1100 2.18E6
1200 9.34E6
1300 3.20E7
1400 9.18E7
1500 2.29E8
1600 5.10E8
1700 1.03E9
1800 1.93E9
1900 3.39E9
2000 5.62E9
2100 8.88E9
2200 1.35E10
2300 1.97E10
2400 2.78E10
2500 3.83E10