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Author(s):   Sadeghi, N.; Kowalczyk, P.; Setser, D.W.
Title:   The CU*(2D5/2) and 2D3/2) chemiluminescent reactions with ClF
Journal:   Phys. Chem. Chem. Phys.
Volume:   5
Page(s):   3443 - 3452
Year:   2003
Reference type:   Journal article
Squib:   2003SAD/KOW3443-3452

Reaction:   Cu(2D3/2) + ClF → Products
Reaction order:   2
Temperature:   300 K
Pressure:  1.33E-4 bar
Rate expression:   1.0x10-10 [±3.0x10-11 cm3/molecule s]
Bath gas:   Ne
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Laser induced fluorescence
Comments:   Measured rate constants for reaction of Cu in ground (2S) and excited states (2D5/2, 2D3/2). Decay of ground state copper measured using atomic resonance absorption at 327.4 nm. Decay of excited state copper measured using LIF at 578.2 nm and 510.6 nm. Absolute rate constants calibrated versus flow rate using decay of Ar(3P2) of 7.4(1.5)E-10 cm3/s as reference. Branching ratios for CuF/CuCl where measured by integrated chemiluminescence signals.

Total pressure 0.1 torr Ne. Used approx. 0.1 mtorr 10% ClF/He. Cu atoms produced by sputter discharge with density approx. 1E11 cm-3.

From vibrational energy disposal, derived Do(CuF) of 34,300 cm-1.

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