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Accessibility information
Author(s):   Matsugi, A.; Suma, K.; Miyoshi, A.
Title:   Deuterium kinetic isotope effects on the gas-phase reactions of C2H with H-2(D-2) and CH4(CD4)
Journal:   Phys. Chem. Chem. Phys.
Volume:   13
Page(s):   4022 - 4031
Year:   2011
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2011MAT/SUM4022-4031

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2011MAT/SUM4022-4031   H2 + ·C2HC2H2 +   297 - 396   2.59E-11       9600   5.38E-13  2
  2011MAT/SUM4022-4031   ·C2H + D2HC≡CD + D  297 - 395   2.21E-11       1.16E04   2.05E-13  2
  2011MAT/SUM4022-4031   CH4 + ·C2HC2H2 + ·CH3  295 - 390   2.32E-11       5600   2.42E-12  2
  2011MAT/SUM4022-4031   CD4 + ·C2HCD3 + HC≡CD  295 - 390   1.66E-11       6900   1.02E-12  2
  2011MAT/SUM4022-4031   CD4 + ·C2HCD3 + HC≡CD  150 - 2000   2.79E-12   1.82   2443   1.04E-12  2
  2011MAT/SUM4022-4031   ·C2H + D2HC≡CD + D  150 - 2000   2.88E-12   1.32   6249   2.31E-13  2
  2011MAT/SUM4022-4031   H2 + ·C2HC2H2 +   150 - 2000   4.12E-12   1.31   5121   5.22E-13  2
  2011MAT/SUM4022-4031   CH4 + ·C2HC2H2 + ·CH3  150 - 2000   4.54E-12   1.58   1731   2.26E-12  2

Search returned 8 records.