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Accessibility information
Author(s):   Hasson, A.S.; Tyndall, G.S.; Orlando, J.J.; Singh, S.; Hernandez, S.Q.; Campbell, S.; Ibarra, Y.
Title:   Branching Ratios for the Reaction of Selected Carbonyl-Containing Peroxy Radicals with Hydroperoxy Radicals
Journal:   J. Phys. Chem. A
Volume:   116
Page(s):   6264 - 6281
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012HAS/TYN6264-6281

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2012HAS/TYN6264-6281   CH3CH2CH2CHO + ·ClHCl + CH3CH2CH2CO  295   0.65              2
  Reference reaction:  CH3CH2CH2CHO + ·Cl → Products 2
  2012HAS/TYN6264-6281   CH3CH2CH2CHO + ·ClHCl + C2H5CH(·)CHO  295   0.08              2
  Reference reaction:  CH3CH2CH2CHO + ·Cl → Products 2
  2012HAS/TYN6264-6281   CH3CH2CH2CHO + ·Cl → CH3CH(·)CH2CHO + HCl  295   0.13              2
  Reference reaction:  CH3CH2CH2CHO + ·Cl → Products 2
  2012HAS/TYN6264-6281   CH3CH2CH2CHO + ·Cl → ·CH2CH2CH2CHO + HCl  295   0.14              2
  Reference reaction:  CH3CH2CH2CHO + ·Cl → Products 2
  2012HAS/TYN6264-6281   C2H5COCH3 + ·ClHCl + CH3C(O)CH(·)CH3  295   0.64              2
  Reference reaction:  C2H5COCH3 + ·Cl → Products 2
  2012HAS/TYN6264-6281   Methacrolein + ·Cl → CH2=C(CH3)CO + HCl  295   0.20              2
  Reference reaction:  Methacrolein + ·Cl → Products 2
  2012HAS/TYN6264-6281   Methacrolein + ·Cl → CH2ClC(·)(CH3)CHO  295   0.80              2
  Reference reaction:  Methacrolein + ·Cl → Products 2
  2012HAS/TYN6264-6281   CH2=CHCOCH3 + ·Cl → CH3C(O)C(·)HCH2Cl  295   0.65              2
  Reference reaction:  CH2=CHCOCH3 + ·Cl → Products 2
  2012HAS/TYN6264-6281   HO2 + CH3C(O)CH2OO· → CH3C(O)CH2OOH + O2  295   0.75              2
  Reference reaction:  HO2 + CH3C(O)CH2OO· → Products 2
  2012HAS/TYN6264-6281   HO2 + CH3C(O)CH2OO· → CH3C(O)CH2O· + ·OH + O2  295   0.25              2
  Reference reaction:  HO2 + CH3C(O)CH2OO· → Products 2
  2012HAS/TYN6264-6281   HO2 + CH3CH2C(O)OO → ·OH + O2 + CH3CH2C(O)O·  295   0.40              2
  Reference reaction:  HO2 + CH3CH2C(O)OO → Products 2
  2012HAS/TYN6264-6281   HO2 + CH3CH2C(O)OO → CH3CH2C(O)OOH + O2  295   0.35              2
  Reference reaction:  HO2 + CH3CH2C(O)OO → Products 2
  2012HAS/TYN6264-6281   HO2 + CH3CH2C(O)OO → C2H5COOH + O3  295   0.25              2
  Reference reaction:  HO2 + CH3CH2C(O)OO → Products 2
  2012HAS/TYN6264-6281   CH3CH2CH2C(O)OO· + HO2O2 + CH3CH2CH2C(O)OOH  295   0.24              2
  Reference reaction:  CH3CH2CH2C(O)OO· + HO2 → Products 2
  2012HAS/TYN6264-6281   CH3CH2CH2C(O)OO· + HO2n-C3H7COOH + O3  295   0.29              2
  Reference reaction:  CH3CH2CH2C(O)OO· + HO2 → Products 2
  2012HAS/TYN6264-6281   CH3CH2CH2C(O)OO· + HO2·OH + O2 + CH3CH2CH2C(O)O·  295   0.47              2
  Reference reaction:  CH3CH2CH2C(O)OO· + HO2 → Products 2
  2012HAS/TYN6264-6281   (CH3)CH(OO·)COCH3 + HO2·OH + O2 + CH3C(O)CH(O·)CH3  295   0.58              2
  Reference reaction:  (CH3)CH(OO·)COCH3 + HO2 → Products 2
  2012HAS/TYN6264-6281   (CH3)CH(OO·)COCH3 + HO2 → O=C(CH3)CH(CH3)OOH + O2  295   0.42              2
  Reference reaction:  (CH3)CH(OO·)COCH3 + HO2 → Products 2
  2012HAS/TYN6264-6281   CH2ClCH(OO)C(O)CH3 + HO2 → CH2ClCH(OOH)C(O)CH3 + O2  295   0.20              2
  Reference reaction:  CH2ClCH(OO)C(O)CH3 + HO2 → Products 2
  2012HAS/TYN6264-6281   CH2ClCH(OO)C(O)CH3 + HO2 → CH2ClCH(O·)C(O)CH3 + ·OH + O2  295   0.80              2
  Reference reaction:  CH2ClCH(OO)C(O)CH3 + HO2 → Products 2
  2012HAS/TYN6264-6281   CH2ClC(CH3)(OO·)CHO + HO2 → CH2ClC(CH3)(O·)CHO + ·OH + O2  295   0.80              2
  Reference reaction:  CH2ClC(CH3)(OO·)CHO + HO2 → Products 2
  2012HAS/TYN6264-6281   CH2ClC(CH3)(OO·)CHO + HO2 → CH2ClC(CH3)(OOH)CHO + O2  295   0.20              2
  Reference reaction:  CH2ClC(CH3)(OO·)CHO + HO2 → Products 2

Search returned 22 records.